Journal of Dalian Maritime University >
2017 , Vol. 43 >Issue 4: 122 - 127
DOI: https://doi.org/10.16411/j.cnki.issn1006-7736.2017.04.018
Experimental study on denitrification from seawater by ultraviolet irradiation
Received date: 2017-05-27
Revised date: 2017-07-19
Online published: 2017-07-20
For improving the denitrification performance of electrolyzed seawater, UV irradiation was introduced to combine with electrolyzed seawater for denitrification. The effect of UV irradiation on denitrification efficiency was investigated based on a UV-bubbling photochemical reactor, and the possible reaction mechanism was discussed preliminarily. Firstly, some contrast experiments for different reaction systems were conducted. Results show that the combination of UV irradiation and electrolyzed seawater can enhance denitrification efficiency significantly. Furthermore, the effects of active chlorine concentration, solution pH value, UV irradiation intensity, and NO inlet concentration on denitrification efficiency of UV irradiated electrolyzed seawater were studied. Results show that denitrification efficiency increases with the increasing of active chlorine concentration in electrolyzed seawater and UV irradiation intensity. The initial pH value of the electrolyzed seawater has little effect on the denitrification performance of the UV irradiated electrolyzed seawater. The denitrification efficiency of the UV irradiated electrolyzed seawater decreases slightly when the NO inlet concentration increasing from 306 mg/m3 to 1534 mg/m3.
HAN Zhi-wei , HAN Zhi-tao , YANG Shao-long , ZHAO Dong-sheng , LIU Bo-jun , PAN Xin-xiang . Experimental study on denitrification from seawater by ultraviolet irradiation[J]. Journal of Dalian Maritime University, 2017 , 43(4) : 122 -127 . DOI: 10.16411/j.cnki.issn1006-7736.2017.04.018
[1] 丁敏,王海霞.船舶大型化发展趋势及其对我国港口业发展的影响[J].中国港口,2013(7):9-12.
[2] ANTES T,SZUDYGA M,SLIWINSKI L,et al.Future needs for ship emission abatement and technical measures[J].Transport Problems,2013,8(3):101-107.
[3] NAIR A,ELIAS S,JOHN V.Performance and emission characteristics of exhaust gas recirculation system and ethanol operation in SI engine[J].European Journal of Advances in Engineering and Technology,2015,2(8): 82-86.
[4] MUELLER L,JAKOBI G,CZECH H,et al.Characteristics and temporal evolution of particulate emissions from a ship diesel engine[J].Applied Energy,2015,155:204-217.
[5] GUO R T,HAO J K,PAN W G, et al. Liquid phase oxidation and absorption of NO from flue gas:a review[J].Separation Science and Technology,2015, 50(2):310-321.
[6] CHU H, CHIEN T W, LI S Y.Simultaneous absorption of SO2 and NO from flue gas with KMnO4/NaOH solutions[J].Science of The Total Environment,2001, 275(1-3):127-135.
[7] 韩粉女,钟秦.H2O2溶液同时脱硫脱硝实验研究[J].环境工程学报,2011(12):2830-2834.
HAN F N,ZHONG Q. Experimental study on simultaneous removal of SO2 and NO by H2O2 solution[J].Chinese Journal of Environmental Engineering,2011:2830-2834.(in Chinese)
[8] LEE H K,DESHWAL B R,YOO K S.Simultaneous removal of SO2 and NO by sodium chlorite solution in wetted-wall column[J].Korean Journal of Chemical Engineering,2005,22(2):208-213.
[9] 赵静,严金英,邱婧伟,等.NaClO2/NaClO复合吸收液同时脱硫脱硝[J].环境工程学报,2012,6(10):3684-3688.
ZHAO J,YAN J Y,QIU J W, et al. Simultaneous removal of SO2 and NO by NaClO2/NaClO compound absorbent[J].Chinese Journal of Environmental Engineering,2012,6(10):3684-3688.(in Chinese)
[10] 郑德康,韩志涛,杨少龙,等.UV辐照强化NaClO2溶液脱硝实验研究[J].化学工程,2017,45(2):45-49.
[11] ZHENG D K,HAN Z T,YANG S L,et al.NO removal by wet scrubbing using UV-irradiated NaClO2 solution[J].Chemical Engineering(China),2017,45(2):45-49.(in Chinese)
[12] AN S H. Air pollution protection onboard by seawater and electrolyte[J].Journal of the Korean Society of Marine Engineering, 2006,30(1):93-101.
[13] YANG S L,HAN Z T,PAN X X,et al.Nitrogen oxide removal using seawater electrolysis in an undivided cell for ocean-going vessels[J].RSC Advances,2016,6(115):114623-114631.
[14] LIU Y X,ZHANG J. Photochemical oxidation removal of NO and SO2 from simulated flue gas of coal-fired power plants by wet scrubbing using UV/H2O2 advanced oxidation process[J].Industrial & Engineering Chemistry Research,2011, 50(7):3836-3841.
[15] YANG S L,HAN Z T,DONG J M,et al.UV-enhanced NaClO oxidation of nitric oxide from simulated flue gas[EB/OL].(2016-02-01)[2017-05-27].http://dx.doi.org/10.1155/2016/6065019.
[16] 韩志涛,于景奇,杨少龙,等.电解海水对模拟船舶柴油机废气的脱硝应用[J].环境科学研究,2017,30(1):144-151.
HAN Z T,YU J Q,YANG S L, et al. Application of electrolyzed seawater for NO removal from simulated marine diesel engine exhaust gas[J].Research of Environmental Sciences,2017,30(1):144-151.(in Chinese)
[17] HAN Z T,YANG S L,PAN X X,et al.New experimental results of NO removal from simulated flue gas by wet scrubbing using NaClO solution[J].Energy Fuels,2017,31(3):3047-3054.
[18] FANG J Y,FU Y,SHANG C. The roles of reactive species in micropollutant degradation in the UV/free chlorine system[J].Environmental Science & Technology,2014,48(3):1859-1868.
[19] NELSON L,RATTIGAN O,NEAVYN R,et al.Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K[J].International Journal of Chemical Kinetics,1990, 22(11):1111-1126.
[20] LIU Y X,ZHANG J,PAN J F, et al. Investigation on the removal of NO from SO2-containing simulated flue gas by an ultraviolet/fenton-like reaction[J].Energy Fuels,2012,26(9):5430-5436.
/
| 〈 |
|
〉 |