Experimental and prediction method for membrane separation efficiency of oily waste water based on LSTM

Expand
  • (Marine Engineering College, Dalian Maritime University, Dalian 116026, China)

Online published: 2025-04-29

Abstract

To explore the separation mechanism and prediction method of ceramic membranes in marine oilwater separators, based on a selfbuilt experimental platform, the effects of oil concentration, membrane pore size and transmembrane pressure difference on separation efficiency and flux were systematically investigated. The results show that regardless of how the concentration, pore size or pressure difference changes, the retention rate is all greater than 99%. However, the flux attenuation is significantly restricted by above three factors, and the order of influence is: oil concentration > transmembrane pressure difference > membrane pore size. Taking a pore size of 1 μm and a pressure difference of 0.10 MPa as an example, when the concentration increases from 50 mg/L to 200 mg/L, the flux attenuation rate increases from 2% to 12%. Take 100 mg/L as an example, when the pressure difference increases from 0.05 MPa to 0.20 MPa, the initial flux can reach 583 L/(m2·h), but the average attenuation rate is 8%. Under the condition of 0.10 MPa, when the pore size increases from 0.5 μm to 2 μm, the flux at high concentration decreases from 368 L/(m2·h) to 312 L/(m2·h), and the attenuation rate reaches 16%. Based on this, a membrane separation effect prediction network FlowLSTM combined with the influence mechanism is proposed. This model effectively alleviates the problems of insufficient screening and loss of historical information by traditional LSTM through spatiotemporal feature extraction, attention fusion and residual connection, and takes the ranking results of key variables as the input to control the model. Compared with the baselines of MLP, RNN, LSTM and GRU, FlowLSTM outperforms the baselines in terms of R2, MSE and MAE indicators. Compared with the original LSTM model, R2 increases by 5%, and MSE and MAE decreases by 21% and 22% respectively.


Cite this article

YU Hengyang, ZHANG Bin . Experimental and prediction method for membrane separation efficiency of oily waste water based on LSTM[J]. Journal of Dalian Maritime University, 2025 , 51(2) : 154 -164 . DOI: 10.16411/j.cnki.issn1006-7736.2025.02.017

References

[1]HOSSEINI M K, LIU L, HOSSEINI P K, et al.  Performance evaluation of a pilot-scale membrane  filtration system for oily wastewater treatment:    CFD modeling and scale-up design[J].Journal of  Water Process Engineering, 2023, 52:103570.
[2]LAY H T, WANG R, CHEW J W. Influence of foulant particle shape on membrane fouling in dead-end microfiltration[J].Journal of Membrane Science, 2022,647:120265.
[3]DU X, LIU Y, MA R, et al. Gravity-driven ceramic membrane (GDCM) filtration treating manganese-contaminated surface water: effects of ozone(O3)-  aided pre-coating and membrane pore size[J]. Chemosphere,2021,279:130603.
[4]王帅帅.电场破乳-动态陶瓷膜串联组合含油污水处理研究[D].北京:北京石油化工学院,2023.DOI: 10.27849/d.cnki.gshyj.2023.000101.
WANG S S. Study on treatment technology of only wastewater by combination of electric field demulsification and dynamic ceremic membrane[D].Beijing: Beijing Institute of Petrochemical Technology, 2023. DOI: 10.27849/d.cnki.gshyj.2023.000101. (in Chinese)
[5]王琰璟.膜过滤过程中甘蔗汁风味物质及特征演变规律的研究[D].南宁:广西大学,2024.DOI:10.27034/d.cnki.ggxiu.2024.000404.
WANG Y J. Sugarcane juice flavor substances during membrane filtration and the study of the characteristic evolution law[D]. Nanning:Guangxi University, 2024.DOI:10.27034/d.cnki.ggxiu.2024.000404. (in Chinese)
[6]张汉泉.亲水性陶瓷复合膜的制备及其分离性能研究[D].广州:华南理工大学,2015.
ZHANG H Q. Preparation of hydrophilic ceramic composite membrane and its separation performance research[D]. Guangzhou: South China University of Technology,2015.(in Chinese)
[7]KRAMER F C, SHANG R, RIETVELD L C, et al. Influence of pH, multivalent counter ions, and membrane fouling on phosphate retention during ceramic nanofiltration[J]. Separation and Purification Technology,2019,227:115675.
[8]张芳,吴鹏,何观伟,等.尿素水解法制备高活性 Cu-Ag/SiO2催化剂及其催化草酸二甲酯加氢性能[J].工业催化,2023,31(7):45-49.
ZHANG F, WU P, HE G W, et al. Highly active Cu-Ag/SiO2 catalysts prepared by urea hydrolysis method in dimethyl oxalate hydrogenation[J]. Industrial Catalysis, 2023,31(7):45-49. (in Chinese)
[9]ABDULLAH S, KARMAKAR S, PRADHAN R C, et al. Pressure‐driven crossflow microfiltration coupled with centrifugation for tannin reduction and clarification of cashew apple juice: Modeling of permeate flux decline and optimization of process parameters[J]. Journal of Food Processing and Preservation, 2022, 46(6): e16497.
[10]USMAN J L, SALAMI B A, GBADAMOSI A, et al. Intelligent optimization for modelling superhydrophobic ceramic membrane oil flux and oil-water separation efficiency: Evidence from wastewater treatment and experimental laboratory[J]. Chemosphere, 2023, 331:138726.
[11]IDRIS I, AHMAD Z, OTHMAN M R, et al. Application of artificial neural network to predict water flux from pre-treated palm oil mill effluent using direct contact membrane distillation[J]. Materialstoday: Proceedings, 2022, 63(Supl.1): S411-S417.
[12]PARK S, SHIM J, YOON N, et al. Deep reinforcement learning in an ultrafiltration system: Optimizing operating pressure and chemical cleaning conditions[J]. Chemosphere, 2022, 308(Part2):136364.
[13]刘耀辉.基于BP神经网络模型的海水淡化反渗透膜污染预测研究[D]. 青岛:青岛理工大学,2023.DOI:10.27263/d.cnki.gqudc.2023.000704.
LIU Y H. Prediction of seawater desalination reverse osmosis membrane contamination based on BP neural netword model[D]. Qingdao: Qingdao University of Technology, 2023. DOI:10.27263/d.cnki.gqudc.2023.000704. (in Chinese)
[14]SHIM J, PARK S, CHO K H. Deep learning model for simulating influence of natural organic matter in nanofiltration[J]. Water Research, 2021, 197:117070.
[15]YOGARATHINAM L T, VELSWAMY K, GANGASALAM A, et al. Performance evaluation of whey flux in dead-end and cross-flow modes via convolutional neural networks[J]. Journal of Environmental Management, 2022, 301:113872.
[16]陈艳,牛亚林,彭兴,等.基于深度学习模型的中试纳滤系统膜污染预测研究[J].兰州交通大学学报,2024,43(5):103-112.
CHEN Y, NIU Y L, PENG X, et al. Prediction of membrane fouling in pilot nanofiltration system based on deep learning model[J]. Journal of Lanzhou Jiaotong University, 2024,43(5):103-112. (in Chinese)
[17]武华华,匡海波,宋扬.基于VMD-FFT-LSTM模型的BDI指数预测[J].大连海事大学学报,2019,45(3):9-16.
WU H H, KUANG H B, SONG Y. Prediction of BDI based on VMD-FFT-LSTM model[J]. Journal of Dalian Maritime University,2019,45(3):9-16. (in Chinese)
[18]EREN M Ş A, ARSLANOĞLU H.α-Alumina (α-Al2O3) ceramic microfiltration membranes in industrial wastewater treatment: Production, design, filtration behavior and performance[J].Ceramics International,2025,51(8):10234-10241. DOI:10.1016/j.ceramin-t.2024.12.454.
[19]MOU Y, CHEN W Z, LIU J G. Total Partial Least Square Regression and its application in infrared spectra- quantitative analysis[J].Measurement, 2025,247:116794.

Outlines

/