大连海事大学学报 >
2018 , Vol. 44 >Issue 2: 126 - 130
DOI: https://doi.org/10.16411/j.cnki.issn1006-7736.2018.02.019
液体氟橡胶的动力黏度
收稿日期: 2017-09-28
修回日期: 2017-10-24
网络出版日期: 2017-11-10
基金资助
国家国际科技合作专项资助项目(2015DFR40500).
Dynamic viscosities of liquid fluoroelastomers
Received date: 2017-09-28
Revised date: 2017-10-24
Online published: 2017-11-10
李东翰 , 廖明义 . 液体氟橡胶的动力黏度[J]. 大连海事大学学报, 2018 , 44(2) : 126 -130 . DOI: 10.16411/j.cnki.issn1006-7736.2018.02.019
The liquid carboxylterminated fluoroelastomer prepared by the oxidative degradation method and the liquid hydroxylterminated fluoroelastomer synthesized by the functionalized method were chosen as studying objects, and the multiple factors influencing the dynamic viscosities of fluoroelastomers were systematically studied by DV2T viscometer. Results show that the monomer compositions of liquid fluoroelastomers have the greatest influence on the dynamic viscosities, and the molecular weights have a greater influence on the dynamic viscosities, and the molecular weight distribution and the type of end groups have little effect on the dynamic viscosities. For the temperature between 30 ℃ ~70 ℃, the dynamic viscosity decreases with the increase of temperature, and when the temperature is 30 ℃~50 ℃, the dynamic viscosity decreases greatly, and when the temperature is above 50 ℃, the dynamic viscosity tends to be stable, which is about 15 Pa·s.
[1]ROBERT C K.Handbook of specialty elastomers[M].New York:Taylor & Francis Group,2008:133 – 153.
[2]AMEDURI B.From vinylidene fluoride(VDF) to the applications of VDF-containing polymers and copolymers: Recent developments and future trends[J].Chemical Reviews,2009,109(12):6632 – 6686.
[3]李东翰,齐士成,张孝阿,等.低分子量含氟聚合物的制备、官能化及特性[J].化学进展,2016,28(5):673 – 685.
LI Dong-han,QI Shi-cheng,ZHANG Xiao-a,et al.Preparation,functionalization and properties of low molecular fluoropolymers[J].Progress in Chemistry,2016,28(5):673 – 685.(in Chinese)
[4]陶慧芬.室温硫化液体氟硅橡胶分子量及其分布的测定研究[J].有机氟工业,1994(4):38 – 40.
TAO Hui-fen.Determination of liquid RTV fluorosilicone rubber and the molecular weight distribution[J].Organo-flnorine Industry,1994(4):38 – 40.(in Chinese)
[5]吴松华,涂洪斌.密闭条件下使用的氟硅密封剂的制备 [J].有机硅材料,2002,16(4):13 – 15.
WU Song-hua,XU Hong-bin.Preparation of fluorosilicone sealants used under airtight condition[J].Silicone Material,2002,16(4):13 – 15.(in Chinese)
[6]MACLACHLAN J D.Fluorocarbon elastomers:a technical review[J].Polymer-Plastics Technology and Engineering,1978,11(1):41 – 53.
[7]李娟,吕亚非,齐士成.端羧基液体氟橡胶的合成及固化性能[J].合成橡胶工业,2014,37(3):188 – 193.
LI Juan,LÜ Ya-fei,QI Shi-cheng.Synthesis and cure properties of liquid fluoroelastomer with carboxyl end group[J].China Synthetic Rubber Industry,2014,37(3):188 – 193.(in Chinese)
[8]刘彩文,吴士军.高聚物流变性能及其测量的研究进展 [J].内蒙古石油化工,2005(2):5 – 8.
LIU Cai-wen,WU Shi-jun.Progress on rheological properties parameters of high polymer and determining[J].Inner Mongolian Petrochemical Industry,2005(2):5 – 8.(in Chinese)
[9]刘斌,谢毅.材料流变性能对注塑制品熔接痕的影响[J].工程塑料应用,2008,36(6):30 – 34.
LIU Bin,XIE Yi.Influence of polymer rheology on weld line of injection-molded products[J].Engineering Plastics Application,2008,36(6):30 – 34.(in Chinese)
[10]何曼君,张红东,陈维孝,等.高分子物理[M].3版.上海:复旦大学出版社,2008:122 – 135.
[11]SAINT-LOUP R,MANSERI A,AMEDURI B,et al.Synthesis and properties of novel fluorotelechelic macrodiols containing vinylidene fluoride, hexafluoropropene and chlorotrifluoroethylene[J].Macromolecules,2002,35(5):1524 – 1536.
[12]LI D H,LIAO M Y.Preparation of telechelic hydroxyl low molecular weight fluoropolymers[J].Key Engineering Materials,2017,753:93 – 98.
[13]史宝萍,王迎春,逯宝娣,等.几种有机液体粘度与温度关系的研究[J].太原科技大学学报,2007,28(6):500 – 503.
SHI Bao-ping,WANG Ying-chun,LU Bao-di,et al.Study on new relationship between viscosity of liquid and temperature[J].Journal of Taiyuan University of Science and Technology,2007,28(6):500 – 503.(in Chinese)
[14]刘煜,李吉明,齐士成.液体含氟橡胶流变性能的研究[J].北京化工大学学报(自然科学版),2011,38(2):48 – 51.
LIU Yu,LI Ji-ming,QI Shi-cheng.Rheological properties of liquid fluororubbers[J].Journal of Beijing University of Chemical Technology(Natural Science),2011,38(2):48 – 51.(in Chinese)
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