材料

碳材料电极在无空穴传输层钙钛矿太阳能电池中的应用进展

  • 尹淑慧 ,
  • 袁颖奇 ,
  • 刘文超 ,
  • 郭明星
展开
  • (大连海事大学 a.理学院;b.环境科学与工程学院,辽宁 大连 116026)
尹淑慧*(1973 — ),女,博士,教授,E-mail:yinsh@dlmu.edu.cn.

收稿日期: 2020-12-01

  修回日期: 2021-01-23

  网络出版日期: 2021-01-23

基金资助

中国科学院大连化学物理研究所国家重点实验室开放课题项目(SKLMRD-K202010;SKLMRD-K202107).

Application progress of hole-transport-material-free perovskite solar cells with carbon materials as counter electrode

  • YIN Shu-hui ,
  • YUAN Ying-qi ,
  • LIU Wen-chao ,
  • GUO Ming-xing
Expand
  • (a. College of Science; b.College of Environment Science and Engineering?,Dalian Maritime University, Dalian 116026, China)

Received date: 2020-12-01

  Revised date: 2021-01-23

  Online published: 2021-01-23

摘要

目前,在高效率钙钛矿太阳能电池(perovskite solar cells,PSCs)中,金、银等贵金属对电极和昂贵的空穴传输材料已成为标配,导致电池成本较高,严重阻碍了钙钛矿太阳能电池的推广与发展,开发价格低廉的对电极及空穴传输材料迫在ü睫.碳材料具有价格低廉、化学性质稳定、导电性好、空穴提取能力强等优点,近年来以其作为无空穴传输层钙钛矿太阳能电池对电极的研究取得了一定的成果.本文介绍了碳基无空穴传输层钙钛矿太阳能电池的器件结构及工作原理,并以碳材料种类为划分依据,分别综述了石墨/炭黑、碳纳米管、导电碳浆、碳墨、石墨烯等多种碳材料作为钙钛矿太阳能电池对电极的研究进展,指出现有研究工作中存在的局限性,并简要说明该领域δ来的发展方向.

本文引用格式

尹淑慧 , 袁颖奇 , 刘文超 , 郭明星 . 碳材料电极在无空穴传输层钙钛矿太阳能电池中的应用进展[J]. 大连海事大学学报, 2021 , 47(2) : 105 -114 . DOI: 10.16411/j.cnki.issn1006-7736.2021.02.012

Abstract

At present, for the highefficient PSCs, the counter electrode based on precious metals like gold and silver and expensive hole transport material are standard configuration, which hinders seriously the promotion and development of PSCs. Therefore, it is urgent to develop lowcost counter electrode and hole transport materials. As well known, the carbon materials possess low price, stable chemical property, good electrical conductivity and strong hole collection ability. In recent years, the research on carbonbased PSCs without hole transport layer (HTL) has developed rapidly. In this paper, the device structure and working principle of carbonbased PSCs were introduced, the application progress of various carbon materials such as graphite/carbon black, carbon nanotubes, conductive carbon paste, carbon ink, grapheme in the counter electrode of perovskite solar cells was reviewed. The limitations of existing research work were pointed out, and the future development directions were briefly described.

参考文献

[1] Kojima A, Teshima K, Shirai Y, et al. Organometal Halide Perovskites as Visible-light Sensitizers for Photovoltaic cells[J]. Journal of the American Chemical Society, 2009, 131(17):6050-6051.
[2] Kim H S, Lee C R, Im J H, et al. Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%[J]. Scientific Reports, 2012, 2: 6022-6025.
[3] https://www.nrel.gov/pv/cell-efficiency.html
[4] Aeineh N, Barea E M, Behjat A, et al. Inorganic Surface Engineering to Enhance Perovskite Solar Cell Efficiency[J]. ACS Applied Materials & Interfaces, 2017, 9(15):13181-13187.
[5] Han G S, Song Y H, Jin Y U, et al. Reduced Graphene Oxide/Mesoporous TiO2 nanocomposite Based Perovskite Solar Cells [J].ACS Applied Materials & Interfaces, 2015, 7(42):23521–23526.
[6] Huang J, Yu X, Xie J, et al. Ambient Engineering for High Performance Organic-Inorganic Perovskite Hybrid Solar Cells [J]. ACS Applied Materials & Interfaces, 2016, 8(33):21505–21511.
[7] Hu R, Chu L, Zhang J, et al. Carbon Materials for Enhancing Charge Transport in the Advancements of Perovskite Solar Cells [J]. Power Sources, 2017, 361: 259-275.
[8] Richard L, McCreery. ChemInform Abstract: Advanced Carbon Electrode Materials for Molecular Electrochemistry [J]. Cheminform , 2010, 39(41).
[9] Laban W A, Etgar L. Depleted Hole Conductor-free Lead Halide Iodide Heterojunction Solar Cells [J]. Energy and Environmental Science, 2013, 6(11): 3249-3253.
[10] Marchioro A, Teuscher J, Friedrich D, et al. Unravelling the Mechanism of Photoinduced Charge Transfer Processes in Lead Iodide Perovskite Solar Cells[J]. Nature Photonics, 2014, 8(3): 250-255.
[11] Ku Z, Rong Y, Xu M, et al. Full Printable Processed Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells with Carbon Counter Electrode[J]. Scientific Reports, 2013, 3, 3132-3137.
[12] Mei A Y, Li X, Liu L F, et al. A Hole-conductor-free, Fully Printable Mesoscopic Perovskite Solar Cell with High Stability[J]. Science, 2014, 345(6194): 295-298.
[13] Hu Y, Si S, Mei A, et al. Stable Large-Area Printable Mesoscopic Perovskite Module Exceeding 10% Efficiency[J]. Solar Rrl, 2017, 1(2):1600019-1600025.
[14] Yang Y Y, Xiao J Y, Wei H Y, et al. An All-carbon Counter Electrode for Highly Efficient Hole-conductor-free Organo-metal Perovskite Solar Cells [J]. RSC Advances, 2014, 4(95):52825-52830.
[15] Zhang L J, Liu T F, Liu L F, et al. The Effect of Carbon Counter Electrodes on Fully Printable Mesoscopic Perovskite Solar Cells[J]. Journal of Materials Chemistry A Materials for Energy & Sustainability, 2015, 3(17): 9165-9170.
[16] Liu Z Y, Zhong Y, Sun B, et al. Novel Integration of Perovskite Solar Cell and Supercapacitor based on Carbon Electrode for Hybridizing Energy Conversion and Storage[J]. Acs Applied Materials & Interfaces, 2017, 9(27): 22361–22368.
[17] Duan M, Rong Y G, Mei A Y, et al. Efficient Hole-conductor-free, Fully Printable Mesoscopic Perovskite Solar Cells with Carbon Electrode Based on Ultrathin Graphite[J]. Carbon, 2017, 120:71-76.
[18] Tian C B, Mei A Y, Zhang S J, et al. Oxygen Management in Carbon Electrode for High-performance Printable Perovskite Solar Cells[J]. Nano Energy, 2018, 53: 160-167.
[19] Hu R Y, Zhang R, Ma Y H, et al. Enhanced Hole Transfer in Hole-conductor-free Perovskite Solar Cells via Incorporating CuS into Carbon Electrodes[J]. Applied Surface Science, 2018, 462(31):840-846.
[20] Bhandari S, Roy A, Ghosh A, et al. Performance of WO3 Incorporated Carbon Electrodes for Ambient Mesoscopic Perovskite Solar Cells [J]. ACS Omega, 2020, 1(5): 422-429
[21] He S S, Qiu L B, Son D Y, et al. Carbon-Based Electrode Engineering Boosts the Efficiency of All Low-Temperature-Processed Perovskite Solar Cells[J]. ACS Energy Letters, 2019, 4(9): 2032-2039.
[22] Yan J Q, Lin S Y, Qiu X C, et al. Accelerated Hole-extraction in Carbon-electrode Based Planar Perovskite Solar Cells by Moisture-assisted Post-annealing[J]. Applied Physics Letters, 2019, 114(10): 103503
[23] Mishra A, Ahmad Z, Zimmermann I, et al. Effect of Annealing Temperature on the Performance of Printable Carbon Electrodes forPerovskite Solar Cells[J]. Organic Electronics, 2019, 65: 375-380.
[24] Li Z, Kulkarni S A, Boix P P, et al. Laminated Carbon Nanotube Networks for Metal Electrode-Free Efficient Perovskite Solar Cells [J]. ACS Nano, 2014, 8(7):6797-6804.
[25] Wang X Y, Li Z, Xu W J, et al. TiO2 Nanotube Arrays Based Flexible Perovskite Solar Cells with Transparent Carbon Nanotube Electrode [J]. Nano Energy, 2015, 11:728-735.
[26] Li H, Cao K, Cui J, et al. 14.7% Efficient Mesoscopic Perovskite Solar Cells Using Single Walled Carbon Nanotubes/Carbon Composite Counter Electrode[J]. Nanoscale, 2016, 8(12): 6379-6385.
[27] Luo Q, Ma H, Zhang Y, et al. Cross-stacked Superaligned Carbon Nanotube Electrodes for Efficient Hole Conductor-free Perovskite Solar Cells[J].Journal of Materials Chemistry A, 2016, 4(15): 5569-5577.
[28] Zheng X L, Chen H N, Li Q, et al. Boron Doping of Multiwalled Carbon Nanotubes Significantly Enhances Hole Extraction in Carbon-Based Perovskite Solar Cells[J]. Nano Letters, 2017, 17(4):2496-2505.
[29] Aitola K, Domanski K, Correa-Baena J P, et al. High Temperature-Stable Perovskite Solar Cell Based on Low-Cost Carbon Nanotube Hole Contact[J].Advanced Materials, 2017, 29(17):1606398.1-1606398.5.
[30] Gopi CV VM, Venkata-Haritha M, Prabakar K, et al. Low-temperature Easy-processed Carbon Nanotube Contact for High-performance Metal- and Hole-transporting Layer-free Perovskite Solar Cells[J]. Journal of Photochemistry and Photobiology A-chemistry, 2017, 332: 265-272.
[31] Yang Y L, Chen H N, Zheng X L, et al. Ultrasound-spray Deposition of Multi-Walled Carbon Nanotubes on NiO Nanoparticles-embedded Perovskite Layers for High-performance Carbon-based Perovskite Solar Cells[J]. Nano Energy, 2017, 42: ?322-333.
[32] Liu S S, Cao K, Hao L, et al. Full Printable Perovskite Solar Cells Based on Mesoscopic TiO2/Al2O3/NiO (Carbon Nanotubes) Architecture[J]. Solar Energy, 2017, 144:158-165.
[33] Hu R Y, Zhang R, Ma Y H, et al. Enhanced Hole Transfer in Hole-conductor-free Perovskite Solar Cells via Incorporating CuS into Carbon Electrodes[J]. Applied Surface Science, 2018, 462(31): 840-846.
[34] Zhou Y, Yin X W, Luo Q, et al. Efficiently Improving the Stability of Inverted Perovskite Solar Cells by Employing Polyethylenimine-Modified Carbon Nanotubes as Electrodes[J]. ACS Applied Materials & Interfaces, 2018, 10(37): 31384-31393.
[35] Siram R B K, Khenkin M V, Niazov-Elkan A, et al. Hybrid Organic Nanocrystal/carbon nanotube Film Electrodes for Air- and Photo-stable Perovskite Photovoltaics[J]. Nanoscale, 2019, 11(8):3733-3740.
[36] Chen J, Chen T, Xu T, et al. MAPbI3 Self-Recrystallization Induced Performance Improvement for Oxygen-Containing Functional Groups Decorated Carbon Nanotube-Based Perovskite Solar Cells[J]. Solar Rrl, 2019, 3(12):197012.
[37] Guo M X, Liu J Q, Yuan Y Y, et al. CNTs/Cf Based Counter Electrode for Hihgly Efficient Hole-transport-material-free Perovskite Solar Cells[J]. Journal of Photochemistry & Photobiology, A: Chemistry, 2020, 403:112843.
[38] Zhang F Q, Yang X C, Wang H X, et al. Structure Engineering of Hole–Conductor Free Perovskite-Based Solar Cells with Low-Temperature-Processed Commercial Carbon Paste As Cathode[J]. ACS Applied Materials & Interfaces, 2014, 6(18): 16140-16146.
[39] Zhou H W, Shi Y T, Dong Q S, et al. Hole-Conductor-Free, Metal-Electrode-Free TiO2/CH3NH3PbI3 Heterojunction Solar Cells Based on a Low-Temperature Carbon Electrode [J]. Journal of Physical Chemistry Letters, 2014, 5(18): 3241-3246.
[40] Zhou H W, Shi Y T, Wang K, et al. Low-Temperature Processed and Carbon-Based ZnO/CH(3)NH(3)Pbl(3)/C Planar Heterojunction Perovskite Solar Cells[J]. Journal of Physical Chemistry C, 2015, 119(9):150216032236005.
[41] Qiang Y, Cheng J, Qi Y, et al. Low-temperature preparation of HTM-free SnO2-based Planar Heterojunction Perovskite Solar Cells with Commercial Carbon as Counter Electrode[J]. Journal of Alloys and Compounds, 2019, 809:UNSP 151817.
[42] Han J H, Yin X W, Zhou Y, et al. High Efficient Large-area Perovskite Solar Cells Based on Paintable Carbon Electrode with NiO Nanocrystal-carbon Intermediate Layer[J]. Chemistry Letters, 2019, 48(7): 734-737.
[43] Zhou X, Wang Y Y, Li C Y, et al. Doping Amino-functionalized Ionic Liquid in Perovskite Crystal for Enhancing Performances of Hole-conductor Free Solar Cells with Carbon Electrode[J]. Chemical Engineering Journal, 2019, 372: 46-52.
[44] Zong B B, Fu W Y, Guo Z A, et al. Highly Stable Hole-conductor-free Perovskite Solar Cells Based upon Ammonium Chloride and a Carbon Electrode[J]. Journal of Colloid and Interface Science, 2019, 540: 315-321.
[45] Yang M, Li J, Li J H, et al. High Efficient and Long-time Stable Planar Heterojunction Perovskite Solar Cells with Doctor-bladed Carbon Electrode[J]. Journal of Power Sources, 2019, 424:61-67.
[46] Wang S W, Liu H J, Bala H, et al. A Highly Stable Hole-conductor-free Cs(x)MA(1-x)PbI(3) Perovskite Solar Cell Based on Carbon Counter Electrode[J]. Electrochimica Acta, 2020, 335:135686.
[47] Sung H, Ahn N, Jang M S, et al. Transparent Conductive Oxide-Free Graphene-Based Perovskite Solar Cells with over 17% Efficiency[J]. Advanced Energy Materials, 2016, 6(3): 1501873.
[48] Yan K Y, Wei Z H, Li J K, et al. High‐Performance Graphene‐Based Hole Conductor‐Free Perovskite Solar Cells: Schottky Junction Enhanced Hole Extraction and Electron Blocking[J]. Small, 2015, 11(19): 2269-2274.
[49] Wei W, Hu B, Jin F, et al. Potassium-chemical synthesis of 3D graphene from CO2 and its excellent performance in HTM-free perovskite solar cells[J]. Journal of Materials Chemistry A, 2017, 5(17): 7749-7752.
[50] Wei Z H, Yan K Y, Chen H N, et al. Cost-efficient Clamping Solar Cells Using Candle Soot for Hole Extraction from Ambipolar Perovskites[J]. Energy & Environmental Science,2014, 7(10):3326-3333.
[51] Gholipour S, Correa-Baena J P, Domanski K, et al. Highly Efficient and Stable Perovskite Solar Cells based on a Low-Cost Carbon Cloth[J]. Advanced Energy Materials, 2016, 6(20): 1601116.
[52] Singh R, Jun H K, Arof A K. Activated Carbon as Back Contact for HTM-free Mixed Cation Perovskite Solar Cell[J]. Phase Transitions, 2018, 91(12): 1268-1276.
[53] Sajid S, Elseman A M, Wei D, et al. NiO@Carbon Spheres: A Promising Composite Electrode for Scalable Fabrication of Planar Perovskite Solar Cells at Low Cost[J]. Nano Energy, 2019, 55: ? 470-476
[54] Mali S S, Kim H, Patil J V, et al. Bio-inspired Carbon Hole Transporting Layer Derived from Aloe Vera Plant for Cost-effective Fully Printable Mesoscopic Carbon Perovskite Solar Cells[J]. ACS Applied Materials & Interfaces, 2018, 10(37): ? 31280-31290
[55] Meng F N, Gao L G, Yan Y L, et al. Ultra-low-cost Coal-based Carbon Electrodes with Seamless Interfacial Contact for Effective Sandwich-structured Perovskite Solar Cells[J]. Carbon, 2020:145: 290-296.
[56] Gao L G, Zhou Y, Meng F N, et al. Several Economical and Eco-friendly Bio-carbon Electrodes for Highly Efficient Perovskite Solar Cells[J]. Carbon, 2020, 162: 267-272.
[57] Pitchaiya S, Eswaramoorthy N, Natarajan M, et al. Perovskite Solar Cells: A Porous Graphitic Carbon based Hole Transporter/Counter Electrode Material Extracted from an Invasive Plant Species Eichhornia Crassipes[J]. Scientific Reports, 2020, 10(1): 6835.
文章导航

/