材料

基于微电子喷墨打印法制备Li4Ti5O12电极及其电化学性能

  • 杨柳 ,
  • 张莉 ,
  • 崔亚军 ,
  • 杜晓梅 ,
  • 黄乃宝 ,
  • 阎景旺
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  • (1.大连海事大学 材料科学与工程系,大连 116026;2.中国昆仑工程有限公司大连分公司,大连 116000;3.中国科学院大连化学物理研究所,大连 116023)
杨柳(1996 — ),女,研究生,研究方向:材料工程.

收稿日期: 2021-02-05

  修回日期: 2021-05-31

  网络出版日期: 2021-05-31

基金资助

大连市科技创新基金资助项目(2018J12GX053).

#br# Preparation and electrochemical properties of Li4Ti5O12electrode based on microelectronic ink jet printing

  • YANG Liu ,
  • ZHANG Li ,
  • CUI Ya-jun ,
  • DU Xiao-mei ,
  • HUANG Nai-bao ,
  • YAN Jing-wang
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  • (1.Department of Materials Science & Engineering, Dalian 116026,China;2.China Kunlun Constructing &Engineering Corporation Dalian Company, Dalian 116000, China;3.Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)

Received date: 2021-02-05

  Revised date: 2021-05-31

  Online published: 2021-05-31

摘要

为解决传统电极制备过程中操作复杂、成本较高等问题,通过微电子喷墨打印结合高温退火的方法,成功制备了不含黏结剂的纯相钛酸锂(LTO)/铜箔(Cu)薄膜电极.扫描电镜分析结果表明:在Cu箔表面可均匀沉积呈纳米颗粒状的纯相LTO;喷墨打印10层活性物质的LTO/Cu薄膜电极与Li片负极组装的扣式电池,在3C(1.0~1.7 V)电流密度下,电池的比容量达91.27 mA·h/g,经过1000次循环后,放电比容量保持率为85.4%,表现出良好的稳定性.上述结果表明,喷墨打印法结合高温退火的方法在制备不含黏结剂的电极材料方面具有广阔的应用前景.

本文引用格式

杨柳 , 张莉 , 崔亚军 , 杜晓梅 , 黄乃宝 , 阎景旺 . 基于微电子喷墨打印法制备Li4Ti5O12电极及其电化学性能[J]. 大连海事大学学报, 2021 , 47(3) : 120 -124 . DOI: 10.16411/j.cnki.issn1006-7736.2021.03.015

Abstract

In order to solve the problems of complicated operation and high cost existing in traditional preparation technology, the pure phase lithium titanate (LTO) / copper foil (Cu) thin film electrode without adhesive was successfully prepared by microelectronic ink jet printing combined with high temperature annealing. Scanning electron microscope analysis results show that the pure phase LTO with nanoparticle shape can be uniformly deposited on the surface of Cu. The button cell assembled with 10 layers of active material LTO / Cu film electrode and Li negative electrode by inkjet printing has a specific capacity of 91.27 mA·h/g at 3C (1.0 ~ 1.7 V) current density, and after 1000 cycles, the retention rate of discharge specific capacity is 85.4%, which show excellent cycle stability. The above results show that the method of inkjet printing combined with high temperature annealing has a broad application prospect in the preparation of electrode materials without adhesive.

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